DEPENDENCE OF THE ADHESIVE STRENGTH OF AN EPOXY COATING ON A STEEL SURFACE ON THE AMOUNTS OF A URETHANE MODIFIER
DOI:
https://doi.org/10.37547/Keywords:
polymer coating, epoxy resin, hydroxylurethane, silicon diurethane, adhesive strength, epoxy number, epoxy equivalent.Abstract
Protective polymer coatings are analyzed. The results of studying the dependence of the adhesive strength of epoxy resin on the amounts of urethane and silicon diurethane modifiers are highlighted. Increasing the ratio of hydroxylurethane:epoxy resin to 15:85, compared with the original size, an increase in adhesive strength by 20%, which is associated with an increase in the proportion of urethane bonds. However, a further increase in the amount of modifying additive (30%) is characterized by the presence of signs, due to the lack of epoxy groups for the formation of a network structure during curing. The epoxy number of this hybrid oligomer is 6.84%, the epoxy equivalent value is 617.3 g/mol. Increasing the curing temperature from 120 to 150ºС significant process duration up to 30 versus 90 minutes. The strength of samples based on silicon diurethane in all temperature ranges and duration of curing practically has the corresponding values with the first samples.
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1.M. Mobin, Hina Shabnam Corrosion Behavior of Mild Steel and SS 304L in Presence of Dissolved Copper. Journal of Minerals and Materials Characterization and Engineering, Vol.9, No.12, 2010. Pp 1113-1130.
2.D.S. Chauhan, V.S. Saji, Heterocyclic Organic Corrosion Inhibitors: Principles and Applications, Elsevier, 2020. P. 298.
3.M.A.J. Mazumder, H. Sheardown, A. Al-Ahmed, Functional Polymers, Springer International Publishing, 2019. P. 1178.
4.Надиров К.С., Есентаева А.А., Биббетова Г.Ж., Жантасов М.К. Антикоррозионные покрытия для нефтепроводов // Нефть и газ. – 2020. - №2.- С. 109-119.
5.Ерофеев В. Т. Полиэфирные полимербетоны каркасной структуры : авт. дис. … канд. техн. наук / В. Т. Ерофеев. – Харьков, 1983. – 23 с.
6.Соломатов В. И. Оптимальные дисперсность и количество наполнителей для полимербетонов, клеев и мастик / В. И. Соломатов, Е. Д. Яхнин, Н. Д. Симонов-Емельянов // Строит. материалы. – 1971.– № 12.– С. 24.
7.Королев А. Я. Снижение адгезионной способности твердых поверхностей / А. Я. Королев, П. В. Давыдов, Л. М. Виноградова // Адгезия полимеров. – М., 1963. – С. 3-11.
8.Жарин Д. Е. Влияние полиизоцианата на физико- механические свойства эпоксидных композитов // Пластические массы. 2002. №7. С. 38-41.
9.Hsieh, K.H., Han, J.L. Graft interpenetrating polymer networks of polyurethane and epoxy. I. Mechanical behavior // J. Polym. Sci., Part B, Polym. Physics. 1990. Vol. 28, no 5. P. 623-630.
10.Raymond, M.P., Bui, V.T. Epoxy/castor oil graft interpenetrating polymer networks // J. Appl. Polym. Sci. 1998. Vol. 70, no. 9. P. 1649-1659.
11.Park, S.J., Jin, J.S. Energetic studies on epoxy–polyurethane interpenetrating polymer networks // J. Appl. Polym. Sci. 2001. Vol. 82, no. 3. P. 775-780.
12.Afzal A, Siddiqi H.M. A comprehensive study of the bicontinuous epoxy – silica hybrid polymers: I. Synthesis, characterization and glass transition// Polymer. 2011. Vol. 52. P. 13450-1355.
13.Absoatov Yu., Khalikov A., Akbarov X. Synthesis of hybrid epoxyurethane coatings and their physicochemical characteristics // Scientific Journal of Mechanics and Technology. 2021. Vol. 3. P. 87-93.
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