EFFECT OF POLYVINYL ALCOHOL ON THE PHYSICO-CHEMICAL PROPERTIES OF BIODEGRADABLE STARCH FILMS
Article Sidebar
Main Article Content
Abstract
Starch-based biodegradable films typically have suboptimal mechanical properties, which restrict their use as food packaging material. However, combining two or more polymers can create new materials with improved functional properties. In this study, blends with varying proportions (0-60%) of polyvinyl alcohol (PVA) were examined to determine the effects on water adsorption, mechanical properties (including the percentage of relative elongation at break and ultimate tensile strength), and thermal properties (Tg). Both polymers were compatible during processing and in the final material for all formulations.
Downloads
Article Details
Section
This work is licensed under a Creative Commons Attribution 4.0 International License.
How to Cite
References
P. Cazón, et al., Polysaccharide-based films and coatings for food packaging: a review, Food Hydrocolloids 68 (2017) 136-148.
K. Mahmood, et al., A review: interaction of starch/non-starch hydrocolloid blending and the recent food applications, Food Biosci. 19 (Supplement C) (2017) 110-120.
Pantyukhina I. E. Method of ancient starch analysis in questions and answers //Multidisciplinary Studies in Archaeology. - 2020. - №. 1. - С. 103-118.
Kostenko V. G., Podzigun G. I., Kovalenok V. A. Optical properties of iodine polysaccharides of wheat starch // Vestnik of Voronezh State University of Engineering Technologies. - 2018. - Т. 80. - №. 4 (78). - С. 288-291.
C. Semeijn, P.L. Buwalda, Chapter 9 - potato starch A2 - Sjöö, Malin, in: L. Nilsson (Ed.), Starch in Food, second ed., Woodhead Publishing, 2018, pp. 353- 372.
Glazacheva E. N. N., Voronova A. A., Uspenskaya M. V. Study of biopolymer film composition based on a mixture of chitosan and gelatin // Izvestiya St. Petersburg State Technological Institute (Technical University). - 2018. - №. 45 (71). - С. 64-68.
A.A. Al-Hassan, M.H. Norziah, Effect of transglutaminase induced crosslinking on the properties of starch/gelatin films, Food Packag Shelf Life 13 (Supplement C) (2017) 15-19.
A. Podshivalov, et al., Gelatin/potato starch edible biocomposite films: correlation between morphology and physical properties, Carbohydr. Polym. 157 (Supplement C) (2017) 1162-1172.
H. Tian, et al., Fabrication and properties of polyvinyl alcohol/starch blend films: effect of composition and humidity, Int. J. Biol. Macromol. 96 (2017) 518-523.
Pavlenok A. V. et al. Preparation and properties of biodegradable composite materials based on polyvinyl alcohol and starch // Vestnik of PO Sukhoi Gomel State Technical University. - 2018. - №. 1 (72). - С. 38- 46.
Ismatova R. A. et al. Development of new composition for sizing cotton yarn //Universum: Technical Sciences. - 2019. - №. 11-3 (68). - С. 82-85.
Krihovets A. V., Slobodyanik G. Packing films with antibacterial properties based on polyvinyl alcohol
//Technology of organic substances. - 2021. - С. 310-312.
Kolpinskaya N. A., Yudaev P. A., Yudaev P. A., Chistyakov E. M. Synthesis3 of polyvinyl alcohol granulated gel // Advances in Chemistry and Chemical Technology. - 2019. - Т. 33. - №. 6 (216). - С. 42-44.
Lebedeva A. V. et al. Study of obtaining nanofibers from aqueous solutions of polyvinyl alcohol by electrospinning // Vestnik of Voronezh State University of Engineering Technologies. - 2022. - Т. 84. - №. 2. - С. 210-220.
G.G. Buonocore, et al., Modeling the lysozyme release kinetics from antimicrobial films intended for food packaging applications, J. Food Sci. 68 (4) (2003) 1365-1370.
C. Curley, et al., An evaluation of the thermal and mechanical properties of a salt- modified polyvinyl alcohol hydrogel for a knee meniscus application, J. Mech. Behav. Biomed. Mater. 40 (2014) 13-22.
X. Tang, S. Alavi, Recent advances in starch, polyvinyl alcohol based polymer blends, nanocomposites and their biodegradability, Carbohydr. Polym. 85 (1) (2011) 7-16.
M. Mucha, S. Ludwiczak, M. Kawinska, Kinetics of water sorption by chitosan and its blends with poly(vinyl alcohol), Carbohydr. Polym. 62 (1) (2005) 42-49.
J.-F. Su, et al., Moisture sorption and water vapor permeability of soy protein isolate/poly(vinyl alcohol)/glycerol blend films, Ind. Crops Prod. 31 (2) (2010) 266-276
V.A. Pereira, I.N.Q. de Arruda, R. Stefani, Active chitosan/PVA films with anthocyanins from Brassica oleraceae (Red Cabbage) as Time-Temperature Indicators for application in intelligent food packaging, Food Hydrocolloids 43 (2015) 180-188.
H.-J. Jo, et al., Development of anti-insect food packaging film containing a polyvinyl alcohol and cinnamon oil emulsion at a pilot plant scale, J. Stored Prod. Res. 61 (2015) 114-118.
R. Jayasekara, et al., Preparation, surface modification and characterisation of solution cast starch PVA blended films, Polym. Test. 23 (1) (2004) 17-27.
A.N. Frone, et al., Thermal properties of water-resistant starch - polyvinyl alcohol films modified with cellulose nanofibers, Polym. Degrad. Stab. 121 (2015) 385- 397.
X. Han, S. Chen, X. Hu, Controlled-release fertilizer encapsulated by starch/ polyvinyl alcohol coating, Desalination 240 (1) (2009) 21-26.
J.W. Lawton, Effect of starch type on the properties of starch containing films, Carbohydr. Polym. 29 (3) (1996) 203-208.
R.Y. Aguirre-Loredo, et al., Effect of airflow presence during the manufacturing of biodegradable films from polymers with different structural conformation, Food Packag Shelf Life 17 (2018) 162-170.
L. Wang, et al., Preparation and characterisation of active films based on chitosan incorporated tea polyphenols, Food Hydrocolloids 32 (1) (2013) 35-41.
Zakirova A. R., Kanarskaya Z. A. A., Kanarsky A. V. Edible packaging materials based on biopolymers // Modern science in the context of modernization processes: problems, realities, prospects. - 2020. - С. 80-86.
Wu, H., Liu, Ch., Chen, J., Chen, Y., Anderson, D.P., Chang, P.R., 2010. Oxidized pea starch/chitosan composite films: structural characterization and properties. J.Appl. Polym. Sci. 118, 3082-3088.
Cano, A., Jimönez, A., Cháfer, M., González, C., Chiralt, A., 2014. Effect of amylose: amylopectin ratio and rice bran addition on starch films properties. Carbohydr. Polym. 111, 543-555.
Chen, J., Liu, Ch., Chen, Y., Chen, Y., Chang, P.R., 2008. Structural characterization and properties of starch/konjac glucomannan blend films. Carbohydr. Polym. 74, 946-952.
Fortunati, E., Puglia, D., Luzi, F., Santulli, C., Kenny, J.M., Torre, L., 2013. Binary PVA bio-nanocomposites containing cellulose nanocrystals extracted from different natural sources: Part I. Carbohydr. Polym. 97, 825- 836.
Bonilla, J., Talon, E., Athars, L., Vargas, M., Chiralt, A., 2013. Effect of the incorporation of antioxidants on physicochemical and antioxidant properties of wheat starch-chitosan films. J. Food Eng. 118, 271-278.
Arvanitoyannis, I.S., 1999. Totally and partially biodegradable polymer blends based on natural and synthetic macromolecules: preparation, physical properties and potential as food packaging materials. J.M.S. Rev. Macromol. Chem. Phys. 39, 205-271.
Chalate, C.M., Halley, P.J.H., Trussb, R.W., 2012. Study on the phase separation of plasticised starch/poly(vinylalcohol)blends. Polym. Degrad. Stabil. 97, 1930- 1939.
K.M. Dean, et al., Key interactions in biodegradable thermoplastic starch/poly (vinyl alcohol)/montmorillonite micro- and nanocomposites, Compos. Sci. Technol. 68 (6) (2008) 1453-1462.
W.-L. Chai, et al., Evaluation of the biodegradability of polyvinyl alcohol/starch blends: a methodological comparison of environmentally friendly materials, J. Polym. Environ. 17 (2) (2009) 71.
L.T. Sin, et al., Detection of synergistic interactions of polyvinyl alcohol-cassava starch blends through DSC, Carbohydr. Polym. 79 (1) (2010) 224-226.
K. Ciesla, et al., The effect of poly(vinyl alcohol) type and radiation treatment on the properties of starch- poly(vinyl alcohol) films, Radiat. Phys. Chem. 141 (2017) 142-148
K. Majdzadeh-Ardakani, B. Nazari, Improving the mechanical properties of thermoplastic starch/poly(vinyl alcohol)/clay nanocomposites, Compos. Sci. Technol. 70 (10) (2010) 1557-1563.
D. Berkün, et al., Sorption and diffusion of water vapour on edible films, J. Therm. Anal. Calorim. 94 (3) (2008) 683-686.
L.J. Mauer, B.F. Ozen, Food packaging, in: Food Processing, Blackwell Publishing, 2008, pp. 101-131